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The Stability of Aryl Carbanions Derived from Pyridine N-Oxide: The Role of Resonance in Stabilizing Aryl Anions
The gas phase stability of carbanions centered at various positions on pyridine N-oxide were investigated by computational and experimental methods. In addition, G3MP2 computations were completed on ring-deprotonated pyridine and N-methylpyridinium. With these species, the effect of a nitrogen-cente...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2802662/ https://ncbi.nlm.nih.gov/pubmed/20000602 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906473v |
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