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Selective Carbanion–Pyridine Coordination of a Reactive P,N Ligand to Rh(I)

Ligands with reactive carbon sites in the periphery of a metal center have emerged as a powerful approach for metal–ligand bond activation. These reactive carbon sites are commonly generated by deprotonation strategies. Carbon–silicon bond cleavage is a potential alternative to access such construct...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Devillard, Marc, Ehlers, Andreas, Siegler, Maxime A., van der Vlugt, Jarl Ivar
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519283/
https://ncbi.nlm.nih.gov/pubmed/30600857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201805504
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