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An Efficient Synthesis of (±)-Grandisol Featuring 1,5-Enyne Metathesis
[Image: see text] An eight step synthesis of (±)-grandisol features a key sequence involving a high-yielding, microwave-assisted enyne metathesis to yield a 1-alkenylcyclobutene that is semihydrogenated to yield a silyl-protected grandisol. Metathesis catalyst screens revealed an intriguing trend wh...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2798917/ https://ncbi.nlm.nih.gov/pubmed/19957923 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo9020375 |
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