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Application of Tandem Ring-Closing Enyne Metathesis: Formal Total Synthesis of (—)-Cochleamycin A
[Image: see text] A tandem ring-closing metathesis of a silaketal-based dienyne substrate proceeded efficiently to provide a bicyclic siloxane, which upon removal of the silicon tether afforded an (E,Z)-1,3-dienediol. Further manipulation of this key functional motif rendered synthesis of the entire...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2715010/ https://ncbi.nlm.nih.gov/pubmed/19507873 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900923c |
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