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Tandem Enyne Metathesis–Metallotropic [1,3]-Shift for a Concise Total Syntheses of (+)-Asperpentyn, (-)-Harveynone, and (-)-Tricholomenyn A
[Image: see text] A tandem reaction sequence involving relay metathesis-induced enyne RCM and metallotropic [1,3]-shift is an effective tool to construct cyclic alkenes with embedded 1,5-dien-3-yne moieties from acyclic precursors containing a 1,3-diyne. Total syntheses of (+)-asperpentyn, (-)-harve...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2647808/ https://ncbi.nlm.nih.gov/pubmed/19115846 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802675j |
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