Allenyl Azide Cycloaddition Chemistry. 2,3-Cyclopentennelated Indole Synthesis through Indolidene Intermediates

[Image: see text] The thermal, photochemical, and photochemical/CuI-mediated cascade cyclizations of a range of substituted 1-(2-azidophenyl)-3-alkenylallenes are described. These reactions provide both 1,2- and 2,3-cyclopentennelated indole products in varying ratios. In most cases, high regioselec...

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Hauptverfasser: Feldman, Ken S., Hester, D. Keith, Iyer, Malliga R., Munson, Paul J., López, Carlos Silva, Faza, Olalla Nieto
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2794409/
https://ncbi.nlm.nih.gov/pubmed/19472993
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900659w
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