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Allenyl Azide Cycloaddition Chemistry: Exploration of the Scope and Mechanism of Cyclopentennelated Dihydropyrrole Synthesis through Azatrimethylenemethane Intermediates

[Image: see text] Detailed studies of the thermal conversion of 1-azidohepta-3,4,6-trienes into cyclopentennelated dihydropyrroles are presented. High levels of diastereoselectivity and regioselectivity are documented. A mechanistic proposal that accounts for all of the diverse results is developed...

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Bibliographic Details
Main Authors: Feldman, Ken S., Iyer, Malliga R., López, Carlos Silva, Faza, Olalla Nieto
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2785442/
https://ncbi.nlm.nih.gov/pubmed/18543966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8008066
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