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Efficient and Stereoselective Synthesis of Yellow Scale Pheromone via Alkyne Haloboration, Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA Reaction), and Pd-Catalyzed Tandem Negishi Coupling

[Image: see text] A Pd-catalyzed reaction of allylzincs with the 1-octyne bromoboration product gives the desired allyl-alkenyl coupling products in good yields except with H(2)C=CHCH(2)ZnBr. This reaction is suitable for converting an alkyne bromoboration product 3 into 4 with no isomerization or β...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Päätekijät: Xu, Zhaoqing, Negishi*, Ei-ichi
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2008
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2774748/
https://ncbi.nlm.nih.gov/pubmed/18763786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8017566
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