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The Nature of the Hydrated Proton H((aq))(+) in Organic Solvents

The nature of H(H(2)O)(n)(+) cations for n = 3 – 8 with weakly basic carborane counterions has been studied by IR spectroscopy in benzene and dichloroethane solution. Contrary to general expectation, neither Eigen-type H(3)O·3H(2)O(+) nor Zundel-type H(5)O(2)(+)·4H(2)O ions are present. Rather, the...

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Bibliografische gegevens
Hoofdauteurs: Stoyanov, Evgenii S., Stoyanova, Irina, Tham, Fook S., Reed, Christopher A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2008
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2773018/
https://ncbi.nlm.nih.gov/pubmed/18700768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803535s
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