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The Nature of the Hydrated Proton H((aq))(+) in Organic Solvents
The nature of H(H(2)O)(n)(+) cations for n = 3 – 8 with weakly basic carborane counterions has been studied by IR spectroscopy in benzene and dichloroethane solution. Contrary to general expectation, neither Eigen-type H(3)O·3H(2)O(+) nor Zundel-type H(5)O(2)(+)·4H(2)O ions are present. Rather, the...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2008
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2773018/ https://ncbi.nlm.nih.gov/pubmed/18700768 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803535s |
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