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The Basicity of Unsaturated Hydrocarbons as probed by H-Bond Acceptor Ability. Bifurcated N–H(+)⋯π Hydrogen Bonding
The competitive substitution of the anion in contact ion pairs of the type [Oct(3)NH(+)]B(C(6)F(5))(4)(−) by unsaturated hydrocarbons L in accordance with the equilibrium Oct(3)NH(+)⋯Anion(−) + nL ↔ [Oct(3)NH(+)⋯L(n)]Anion(−) has been studied in CCl(4) solution. On the basis of equilibrium constants...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2730148/ https://ncbi.nlm.nih.gov/pubmed/18637650 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.200800337 |
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