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Convenient Access to Bicyclic and Tricyclic Diazenes
[Image: see text] Heating the tosylhydrazone of an ω-alkenyl ketone or aldehyde to reflux in toluene in the presence of K(2)CO(3) delivered the bicyclic diazene. Irradiation of the diazene converted it to the cyclopropane. This appears to be a generally useful method for the construction of substitu...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2765546/ https://ncbi.nlm.nih.gov/pubmed/18980330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8017704 |
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