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Concerted Proton-Electron Transfer in a Ruthenium Terpyridyl-Benzoate System with a Large Separation between the Redox and Basic Sites

In order to understand how the separation between the electron and proton-accepting sites affects proton-coupled electron transfer (PCET) reactivity, we have prepared ruthenium complexes with 4′-(4-carboxyphenyl)terpyridine ligands, and studied reactivity with hydrogen atom donors (H-X). Ru(II)(pydi...

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Détails bibliographiques
Auteurs principaux: Manner, Virginia W., Mayer, James M.
Format: Artigo
Langue:Inglês
Publié: 2009
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2765064/
https://ncbi.nlm.nih.gov/pubmed/19569636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja902942g
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