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Allylic C—H Amination for the Preparation of syn-1,3-Amino Alcohol Motifs

A highly selective and general Pd/sulfoxide-catalyzed allylic C—H amination reaction en route to syn-1,3-amino alcohol motifs is reported. Key to achieving this reactivity under mild conditions is the use of electron-deficient N-nosyl carbamate nucleophiles that are thought to promote functionalizat...

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Detalhes bibliográficos
Main Authors: Rice, Grant T., White, M. Christina
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2751616/
https://ncbi.nlm.nih.gov/pubmed/19645489
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9054959
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