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Catalytic Enantioselective Allylation of Dienals Through the Intermediacy of Unsaturated π-Allyl Complexes
[Image: see text] The nickel-catalyzed enantioselective addition of allylboronic acid pinacol ester - allylB(pin) – to α,β,γ,δ-unsaturated aldehydes is described. This reaction results in a remarkable inversion in substrate olefin geometry providing the Z,E configured reaction product in good enanti...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2750882/ https://ncbi.nlm.nih.gov/pubmed/19678681 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9058537 |
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