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Insertion of a Bulky Rhodium Complex into a DNA Cytosine-Cytosine Mismatch: An NMR Solution Study
The bulky octahedral complex, Rh(bpy)(2)chrysi(3+) (chrysi = 5, 6- chrysenequinone diimine), binds single base mismatches in a DNA duplex with micromolar binding affinities and high selectivity. Here we present an NMR solution study to characterize the binding mode of this bulky metal complex with i...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2748819/ https://ncbi.nlm.nih.gov/pubmed/17877349 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0739436 |
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