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Radical-mediated thiodesulfonylation of the vinyl sulfones: Access to (α-fluoro)vinyl sulfides

Radical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (α-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of...

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Bibliographic Details
Main Authors: Sacasa, Pablo R., Zayas, Jessica, Wnuk, Stanislaw F.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2748331/
https://ncbi.nlm.nih.gov/pubmed/20161068
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.07.063
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