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Catalytic Asymmetric Stetter Reaction Onto Vinylphosphine Oxides and Vinylphosphonates

[Image: see text] An intramolecular Stetter reaction of vinylphosphine oxides and vinylphosphonates has been developed. Treatment of an aldehyde with a nucleophilic N-heterocyclic carbene catalyst allows for addition of an acyl anion equivalent into a vinylphosphine oxide or vinylphosphonate Michael...

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Dettagli Bibliografici
Autori principali: Cullen, Steven C., Rovis, Tomislav
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2008
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2746454/
https://ncbi.nlm.nih.gov/pubmed/18549233
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801047k
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