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Catalytic Asymmetric Intermolecular Stetter Reaction of Enals with Nitroalkenes: Enhancement of Catalytic Efficiency Through Bifunctional Additives
An asymmetric intermolecular Stetter reaction of enals with nitroalkenes, catalyzed by chiral N-heterocyclic carbenes, has been developed. Reaction rate and efficiency are profoundly impacted by the presence of catechol. The reaction proceeds with high selectivities affording good yields of the Stet...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3147302/ https://ncbi.nlm.nih.gov/pubmed/21678918 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja203810b |
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