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A Unified Strategy for Enantioselective Total Synthesis of Cladiellin and Briarellin Diterpenes: Total Synthesis of Briarellins E and F, and the Putative Structure of Alcyonin and Revision of Its Structure Assignment

Enantioselective total syntheses of briarellin E (12) and briarellin F (13), as well as the structure originally proposed for the cladiellin diterpene alcyonin (10), have been realized. Comparison of the spectral data for synthetic 10, natural alcyonin, cladiellisin (33), and cladiellaperoxide (34),...

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Detalhes bibliográficos
Main Authors: Corminboeuf, Olivier, Overman, Larry E., Pennington, Lewis D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2744073/
https://ncbi.nlm.nih.gov/pubmed/19534538
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo9010156
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