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Seleniranium Ion-Triggered Reactions - New Aspects of Friedel-Crafts and N-Detosylative Cyclizations
[Image: see text] Seleniranium ions at low temperatures (-90 to -78 °C) will initiate effective Friedel-Carfts cyclization if a suitably placed arene is allowed to react even when the arene is unactivated. These intermediates generated from N-aryl-N-tosylamides, undergo a novel, surprisingly efficie...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2742950/ https://ncbi.nlm.nih.gov/pubmed/19507847 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900961m |
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