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Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

[Image: see text] A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as active species.

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Detalhes bibliográficos
Main Authors: Hull, Jonathan F., Balcells, David, Blakemore, James D., Incarvito, Christopher D., Eisenstein, Odile, Brudvig, Gary W., Crabtree, Robert H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2742501/
https://ncbi.nlm.nih.gov/pubmed/19496565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja901270f
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