Electron-Rich CpIr(biphenyl-2,2′-diyl) Complexes with π–Accepting Carbon Donor Ligands

Cp*Ir(III) and CpIr(III) complexes have attracted interest as catalysts for oxidative transformations, and highly oxidizing iridium species are postulated as key intermediates in both catalytic water and C–H bond oxidation. Strongly electron-donating ligand sets have been shown to stabilize Ir(IV) c...

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Hlavní autoři: Graeupner, Jonathan, Brewster, Timothy P., Blakemore, James D., Schley, Nathan D., Thomsen, Julianne M., Brudvig, Gary W., Hazari, Nilay, Crabtree, Robert H.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3902143/
https://ncbi.nlm.nih.gov/pubmed/24474841
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om300696t
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