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Influence of Hydration on Proton Transfer in the Guanine-Cytosine Radical Cation (G(•+)-C) Base Pair: A Density Functional Theory Study
On one-electron oxidation all molecules including DNA bases become more acidic in nature. For the GC base pair experiments suggest that a facile proton transfer takes place in the G(•+)-C base pair from N(1) of G(•+) to N(3) of cytosine. This intra-base pair proton transfer reaction has been extensi...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2740929/ https://ncbi.nlm.nih.gov/pubmed/19485319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp903403d |
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