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Sugar Radical Formation by a Proton Coupled Hole Transfer in 2′-Deoxyguanosine Radical Cation (2′-dG(•+)): A Theoretical Treatment

Previous experimental and theoretical work has established that electronic excitation of a guanine cation radical in nucleosides or in DNA itself leads to sugar radical formation by deprotonation from the dexoxyribose sugar. In this work we investigate a ground electronic state pathway for such suga...

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Autors principals: Kumar, Anil, Sevilla, Michael D.
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2765868/
https://ncbi.nlm.nih.gov/pubmed/19754084
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp9058593
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