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On the Stereochemistry of the Kulinkovich Cyclopropanation of Nitriles
The stereochemistry of the Kulinkovich cyclopropanation of nitriles with alkenes has been examined by employing (E)-disubstituted alkenes and deuterium-labeled homoallylic alcohols as a stereochemical probe. An intramolecular cyclopropanation proceeds with preservation of the olefin configuration. O...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2739442/ https://ncbi.nlm.nih.gov/pubmed/19527011 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900823h |
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