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On the Stereochemistry of the Kulinkovich Cyclopropanation of Nitriles

The stereochemistry of the Kulinkovich cyclopropanation of nitriles with alkenes has been examined by employing (E)-disubstituted alkenes and deuterium-labeled homoallylic alcohols as a stereochemical probe. An intramolecular cyclopropanation proceeds with preservation of the olefin configuration. O...

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Bibliografiset tiedot
Päätekijät: Astashko, Dmitry, Lee, Hyung Goo, Bobrov, Denis N., Cha, Jin K.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2009
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2739442/
https://ncbi.nlm.nih.gov/pubmed/19527011
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900823h
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