Dechalcogenative Allylic Selenosulfide And Disulfide Rearrangements: Complementary Methods For The Formation Of Allylic Sulfides In The Absence Of Electrophiles. Scope, Limitations, And Application To The Functionalization Of Unprotected Peptides In Aqueous Media

[Image: see text] Primary allylic selenosulfates (seleno Bunte salts) and selenocyanates transfer the allylic selenide moiety to thiols giving primary allylic selenosulfides, which undergo rearrangement in the presence of PPh(3) with the loss of selenium to give allylically rearranged allyl alkyl su...

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Bibliografiske detaljer
Main Authors: Crich, David, Krishnamurthy, Venkataramanan, Brebion, Franck, Karatholuvhu, Maheswaran, Subramanian, Venkataraman, Hutton, Thomas K.
Format: Artigo
Sprog:Inglês
Udgivet: 2007
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2729405/
https://ncbi.nlm.nih.gov/pubmed/17655306
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja072969u
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