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New synthetic strategies for the stereocontrolled synthesis of substituted “skipped” diepoxides
This report describes a number of new synthetic approaches towards methyl-substituted mono- and diepoxy alcohols that serve as substrates for endo-selective epoxide-opening cascades. The key transformations involve the manipulation of alkynes. Highlighted are the directed methylmetalation of bishomo...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2724682/ https://ncbi.nlm.nih.gov/pubmed/20161178 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.05.074 |
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