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Evolving biosynthetic tangos negotiate mechanistic landscapes
The dependence of polyketide synthase and terpene cyclase mechanistic adaptation on the chemistry of their oligomeric substrates illuminates a convergent evolutionary strategy for shaping cyclization in these otherwise disparate reactions. Evolution of these enzyme families relies on rhythmic tangos...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2703434/ https://ncbi.nlm.nih.gov/pubmed/18347585 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchembio0408-217 |
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