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Synthesis of the AB Subunit of Angelmicin B through a Tandem Alkoxy Radical Fragmentation-Etherification Sequence
[Image: see text] The synthesis of the tricyclic enone 2, corresponding to the AB subunit of the novel tyrosine kinase inhibitor angelmicin B, is described. The strategy centers on an intramolecular Diels—Alder (IMDA) reaction on triene 4 to provide the complex decalin 3, which is elaborated to 2. O...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2692225/ https://ncbi.nlm.nih.gov/pubmed/18324819 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol703036y |
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