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Diastereoselective Construction of Functionalized Homoallylic Alcohols by Ni-Catalyzed Diboron-Promoted Coupling of Dienes and Aldehydes

[Image: see text] The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereo-selective fashion employing a stoichiometric amount of bis(pinacolato)diboron. This reductive coupling furnishes an allyl boronic esters as the reaction product, a compound which was readi...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Cho, Hee Yeon, Morken, James P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2008
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2676113/
https://ncbi.nlm.nih.gov/pubmed/18998642
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja806113v
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