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Ni-Catalyzed Borylative Diene-Aldehyde Coupling: The Remarkable Effect of P(SiMe(3))(3)

[Image: see text] The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio-and stereo-selective fashion employing a stoichiometric amount of bis(pinacolato)diboron. In the presence of P(SiMe(3))(3), this reductive coupling furnishes allyl boronic esters which are regioisomer...

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Bibliografske podrobnosti
Main Authors: Cho, Hee Yeon, Morken, James P.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2912217/
https://ncbi.nlm.nih.gov/pubmed/20481451
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101513d
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