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Ni-Catalyzed Borylative Diene-Aldehyde Coupling: The Remarkable Effect of P(SiMe(3))(3)
[Image: see text] The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio-and stereo-selective fashion employing a stoichiometric amount of bis(pinacolato)diboron. In the presence of P(SiMe(3))(3), this reductive coupling furnishes allyl boronic esters which are regioisomer...
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2010
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2912217/ https://ncbi.nlm.nih.gov/pubmed/20481451 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101513d |
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