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Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp(2)Zr(H)Cl
[Image: see text] Allenes can be synthesized via the direct S(N)2′ addition of hydride to propargylic alcohols. Previous examples of this approach, however, have involved harsh reaction conditions and have suffered from incomplete transfer of central chirality to axial chirality. Here we show that C...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2668978/ https://ncbi.nlm.nih.gov/pubmed/18652467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8035527 |
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