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Multicomponent Synthesis of α-Branched Amides

[Image: see text] α-Branched amides are prepared by multicomponent reactions in which nitriles undergo hydrozirconation to form metalloimines that react with acyl chlorides. The resulting acylimines react with a variety of π-nucleophiles in the presence of Lewis acids to form the desired amides.

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Bibliografiske detaljer
Main Authors: DeBenedetto, Mikkel V., Green, Michael E., Wan, Shuangyi, Park, Jung-Hyun, Floreancig, Paul E.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2665885/
https://ncbi.nlm.nih.gov/pubmed/19152262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802764j
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