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Efficient Boron-Copper Additions to Aryl-Substituted Alkenes Promoted by NHC–Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

A Cu-catalyzed method for efficient boron-copper addition processes involving acyclic and cyclic disubstituted aryl olefins are reported. Reactions are promoted with 0.5–5 mol % of a readily available N-heterocyclic carbene (NHC) complex; the presence of MeOH promotes in situ protonation of the C–Cu...

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Bibliografiske detaljer
Main Authors: Lee, Yunmi, Hoveyda, Amir H.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2662741/
https://ncbi.nlm.nih.gov/pubmed/19256564
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809382c
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