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Asymmetric bis-Boranes as Bidentate Catalysts for Carbonyl Substrates

[Image: see text] A new class of C(2) symmetric bis-oxazaborolidinone is described. These compounds exhibit bidentate binding to carbonyl substrates. Using the Diels-Alder reaction the catalytic activity of these bis-Lewis acids is probed. Reaction rates and selectivities are observed that exceed th...

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Hlavní autoři: Rodriguez, Andrew A., Zhao, Carrie, Shea, Kenneth J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2662717/
https://ncbi.nlm.nih.gov/pubmed/19175350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802793k
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