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Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination
In situ combination of diphosphinic amides and Zr(NMe(2))(4) results in the formation of chiral zirconium bis(amido) complexes. The complexes are competent catalysts for intramolecular asymmetric alkene hydroamintion, providing piperidines and pyrrolidines in up to 80% ee and high yield. This system...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2600731/ https://ncbi.nlm.nih.gov/pubmed/19079735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0606791 |
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