A Highly Reactive Titanium Precatalyst for Intramolecular Hydroamination Reactions

[Image: see text] Tetrakisamido titanium complexes are significantly more active than Cp(2)TiMe(2) (1) in the intramolecular hydroamination of aminoalkynes and aminoallenes. In the latter case, the regioselectivity of the transformation depends on the nature of the precatalyst, yielding the most sel...

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Detalhes bibliográficos
Main Authors: Ackermann, Lutz, Bergman*, Robert G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2002
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1575920/
https://ncbi.nlm.nih.gov/pubmed/11975607
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https://ncbi.nlm.nih.gov/pmc/articles/PMC1575920/
https://ncbi.nlm.nih.gov/pubmed/11975607