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Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations

A new class of bis‐cyclometalated rhodium(III) catalysts containing two inert cyclometalated 6‐tert‐butyl‐2‐phenyl‐2H‐indazole ligands and two labile acetonitriles is introduced. Single enantiomers (>99 % ee) were obtained through a chiral‐auxiliary‐mediated approach using a monofluorinated salic...

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Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Steinlandt, Philipp S., Zuo, Wei, Harms, Klaus, Meggers, Eric
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6916287/
https://ncbi.nlm.nih.gov/pubmed/31541505
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903369
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