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Synthesis of (+)-Coronafacic Acid

[Image: see text] An enantioselective synthesis of (+)-coronafacic acid has been achieved. Rhodium catalyzed cyclization of an α-diazoester provided the intermediate cyclopentanone in high enantiomeric purity. Subsequent Fe-mediated cyclocarbonylation of a derived alkenyl cyclopropane gave a bicycli...

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Hlavní autoři: Taber, Douglass F., Sheth, Ritesh B., Tian, Weiwei
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2662389/
https://ncbi.nlm.nih.gov/pubmed/19231870
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo802493k
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