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Synthesis of (+)-Coronafacic Acid
[Image: see text] An enantioselective synthesis of (+)-coronafacic acid has been achieved. Rhodium catalyzed cyclization of an α-diazoester provided the intermediate cyclopentanone in high enantiomeric purity. Subsequent Fe-mediated cyclocarbonylation of a derived alkenyl cyclopropane gave a bicycli...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2662389/ https://ncbi.nlm.nih.gov/pubmed/19231870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo802493k |
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