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Unusually Reactive and Selective Carbonyl Ylides for Three-Component Cycloaddition Reactions
Conditions are described for the Rh-catalyzed formation of highly-functionalized dihydro-and tetrahydrofuran products via three-component reactions of aldehydes, α-alkyl-α-diazoesters, and dipolarophiles. The alkyl-substituted carbonyl ylides that are generated in this fashion are highly reactive in...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2659807/ https://ncbi.nlm.nih.gov/pubmed/19128053 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807184r |
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