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HIGHLY DIASTEREOSELECTIVE SYNTHESIS OF NUCLEOSIDE ADDUCTS FROM THE CARCINOGENIC BENZO[a]PYRENE DIOL EPOXIDE AND A COMPUTATIONAL ANALYSIS
A diastereoselective synthesis of the nucleoside adducts corresponding to a cis ring opening of the carcinogen (±)-7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (BaP DE-2) by 2’-deoxyadenosine and 2’-deoxyguanosine is described. The key intermediate (±)-10α-amino-7β,8α,9α-trihydroxy...
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| Autori principali: | , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2007
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2659345/ https://ncbi.nlm.nih.gov/pubmed/17199284 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja063902u |
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