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Reaction of AdoMet with ThiC generates a backbone free radical
ThiC is an [4Fe-4S] cluster protein that catalyzes the formation of 4-amino-5-hydroxymethyl-2-methylpyrimidine. EPR spectroscopic studies demonstrate that, upon interaction with AdoMet, active ThiC from Salmonella enterica generates a persistent free radical on the α-carbon of an amino acid residue....
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2654281/ https://ncbi.nlm.nih.gov/pubmed/19113839 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi802154j |
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