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Catalytic Redox-Initiated Glycolate Aldol Additions of Silyl Glyoxylates
[Image: see text] Lanthanide triisopropoxides catalyze a rapid, tandem MPV reduction/Brook rearrangement/aldol sequence between silyl glyoxylates and aldehydes that achieves catalytic turnover through alkoxide transfer from a strain-release Lewis acidic silacycle.
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2651742/ https://ncbi.nlm.nih.gov/pubmed/19161319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802828d |
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