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A Secondary Kinetic Isotope Effect Study of the 1-Deoxy-d-xylulose-5-phosphate Reductoisomerase-catalyzed Reaction: Evidence for a Retroaldol-Aldol Rearrangement

[Image: see text] 1-Deoxy-d-xylulose 5-phosphate (DXP) reductoisomerase (DXR, also known as methyl-d-erythritol 4-phosphate (MEP) synthase) is a NADPH-dependent enzyme, which catalyzes the conversion of DXP to MEP in the non-mevalonate pathway of isoprene biosynthesis. Two mechanisms have been propo...

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Bibliografiske detaljer
Main Authors: Munos, Jeffrey W., Pu, Xiaotao, Mansoorabadi, Steven O, Kim, Hak Joong, Liu, Hung-wen
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2650392/
https://ncbi.nlm.nih.gov/pubmed/19159292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807987h
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