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Siloxacyclopentenes as Dienophile-Linked Directing Groups in Intramolecular Diels-Alder Reactions

[Image: see text] The synthesis and intramolecular Diels-Alder reactions of trienes 5 and 6 with a siloxacyclopentene-constrained dienophile are described. These reactions provide the primary cycloadducts 7 and 8 with high diastereoselectivity. These cycloadducts possess trans-relationships between...

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Bibliografiset tiedot
Päätekijät: Halvorsen, Geoff T., Roush, William R.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2008
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2650085/
https://ncbi.nlm.nih.gov/pubmed/18954061
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802266s
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