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Intramolecular Diels-Alder Reactions of Siloxacyclopentene Constrained Trienes
[Image: see text] The synthesis of siloxacyclopentene-constrained trienes 7 and 10 and studies of their IMDA cycloadditions are described. The use of appropriately chosen thermal or Lewis-acid conditions allows for cycloadducts 3-6 to be obtained with high levels of diastereoselectivity. These adduc...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2504012/ https://ncbi.nlm.nih.gov/pubmed/17480094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070858u |
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