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Intramolecular Diels-Alder Reactions of Siloxacyclopentene Constrained Trienes

[Image: see text] The synthesis of siloxacyclopentene-constrained trienes 7 and 10 and studies of their IMDA cycloadditions are described. The use of appropriately chosen thermal or Lewis-acid conditions allows for cycloadducts 3-6 to be obtained with high levels of diastereoselectivity. These adduc...

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Autors principals: Halvorsen, Geoff T., Roush, William R.
Format: Artigo
Idioma:Inglês
Publicat: 2007
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2504012/
https://ncbi.nlm.nih.gov/pubmed/17480094
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070858u
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